SYNTHESIS OF 2-HYDROXY-3-METHYL-2-CYCLOPENTENONE, CORYLONE, FROM 2-KETOGLUTARIC ACID

被引：4

作者：

DOSSANTOS, ML ^{[1
]}

DEMAGALHAES, GC ^{[1
]}

机构：

[1] UNIV BRASILIA, DEPT QUIM, BR-70910 BRASILIA, DF, BRAZIL

来源：

SYNTHETIC COMMUNICATIONS | 1991年 / 21卷 / 17期

关键词：

D O I：

10.1080/00397919108021577

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of 2-ketoglutaric acid with diazomethane gave 2-(methoxycarbonyl)-oxiranepropanoic acid methyl ester (2) which lead to 2-hydroxy-2-methyl-glutaric acid dimethyl ester (3) by catalytic hydrogenation, which was further processed to the title compound.

引用

页码：1783 / 1788

页数：6

共 7 条

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[7] SYNTHETIC ROUTES TO 2-HYDROXY-3-METHYLCYCLOPENT-2-EN-1-ONE AND RELATED CYCLOPENTANE-1,2-DIONES - A REVIEW
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