TETRATHIORHENATE(VI), RES4(2-) - SPECTROELECTROCHEMICAL CHARACTERIZATION (UV VIS IR) OF A SMALL NEW D(1) SYSTEM AND OF ITS TETRAKIS(2,2'-BIPYRIDINE)DIRUTHENIUM(II) COMPLEX (EPR)

被引：24

作者：

SCHAFER, R

KAIM, W

MOSCHEROSCH, M

KREJCIK, M

机构：

[1] UNIV STUTTGART, INST ANORGAN CHEM, PFAFFENWALDRING 55, W-7000 STUTTGART 80, GERMANY

[2] CZECHOSLOVAK ACAD SCI, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, CS-18223 PRAGUE, CZECHOSLOVAKIA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 11期

关键词：

D O I：

10.1039/c39920000834

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

ReS42- is the first d1 tetrathiometallate persistent enough to be studied with respect to change transfer, ligand field and IR vibrational spectra via spectroelectrochemistry; an EPR spectrum could only be detected of its trinuclear derivative [(bpy)2Ru(mu-ReS4)Ru(bpy)2]2+ (bpy = 2,2'-bipyridine) at 4 K.

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页码：834 / 835

页数：2

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