CHROMOGENIC CALIX[4]ARENE AS IONOPHORE FOR POTENTIOMETRIC AND OPTICAL SENSORS

被引：75

作者：

TOTH, K ^{[1
]}

LAN, BTT ^{[1
]}

JENEY, J ^{[1
]}

HORVATH, M ^{[1
]}

BITTER, I ^{[1
]}

GRUN, A ^{[1
]}

AGAI, B ^{[1
]}

TOKE, L ^{[1
]}

机构：

[1] TECH UNIV BUDAPEST,DEPT ORGAN CHEM TECHNOL,H-1521 BUDAPEST,HUNGARY

来源：

TALANTA | 1994年 / 41卷 / 06期

关键词：

D O I：

10.1016/0039-9140(94)E0094-8

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Chromogenic calix[4]arene derivative was synthesized and tested as an ionophore for potentiometric and optical sensors. Distinct sodium selectivity was observed with this ionophore based, plasticized PVC membranes in potentiometric measurements suggesting their utility for biological applications. Optode membranes exhibited sodium sensitivity in the 5 x 10(-2)-10(-4)M concentration range. The optical sensitivity was improved by the use of an internal, lipophilic base (TDDA). The operation of the optical sensor is in accordance with the ion-exchange theory.

引用

页码：1041 / 1049

页数：9

共 30 条

[21] THEORETICAL ASPECTS OF BULK OPTODE MEMBRANES [J].

SEILER, K ;

SIMON, W .

ANALYTICA CHIMICA ACTA, 1992, 266 (01) :73-87

[22] DESIGN AND CHARACTERIZATION OF A NOVEL AMMONIUM ION-SELECTIVE OPTICAL SENSOR BASED ON NEUTRAL IONOPHORES [J].

SEILER, K ;

MORF, WE ;

RUSTERHOLZ, B ;

SIMON, W .

ANALYTICAL SCIENCES, 1989, 5 (05) :557-561

[23] CHEMICAL SENSORS BASED ON FIBER OPTICS [J].

SEITZ, WR .

ANALYTICAL CHEMISTRY, 1984, 56 (01) :A16-&

[24] CHROMOGENIC CALIX[4] ARENE [J].

SHIMIZU, H ;

IWAMOTO, K ;

FUJIMOTO, K ;

SHINKAI, S .

CHEMISTRY LETTERS, 1991, (12) :2147-2150

[25] FIBER-OPTIC MAGNESIUM AND CALCIUM-ION SENSOR BASED ON A NATURAL CARBOXYLIC POLYETHER ANTIBIOTIC [J].

SUZUKI, K ;

TOHDA, K ;

TANDA, Y ;

OHZORA, H ;

NISHIHAMA, S ;

INOUE, H ;

SHIRAI, T .

ANALYTICAL CHEMISTRY, 1989, 61 (04) :382-384

[26] FIBEROPTIC POTASSIUM-ION SENSORS BASED ON A NEUTRAL IONOPHORE AND A NOVEL LIPOPHILIC ANIONIC DYE [J].

SUZUKI, K ;

OHZORA, H ;

TOHDA, K ;

MIYAZAKI, K ;

WATANABE, K ;

INOUE, H ;

SHIRAI, T .

ANALYTICA CHIMICA ACTA, 1990, 237 (01) :155-164

[27]

TELTING-DIAZ M, 1989, Analytical Proceedings, V26, P29, DOI 10.1039/ap9892600029

[28]

Ungaro R., 1984, J INCLUSION PHENOM, V2, P199, DOI DOI 10.1007/BF00663257

[29] CHARACTERIZATION OF AN OPTODE MEMBRANE FOR ZINC(II) INCORPORATING A LIPOPHILIZED ANALOG OF THE DYE 4-(2-PYRIDYLAZO)RESORCINOL [J].

WANG, KM ;

SEILER, K ;

RUSTERHOLZ, B ;

SIMON, W .

ANALYST, 1992, 117 (01) :57-60

[30] OPTICAL SENSOR FOR SODIUM BASED ON ION-PAIR EXTRACTION AND FLUORESCENCE [J].

ZHUJUN, Z ;

MULLIN, JL ;

SEITZ, WR .

ANALYTICA CHIMICA ACTA, 1986, 184 :251-258

← 1 2 3 →