RADIATION EFFECTS IN HOMOGENEOUS CATALYSIS - COBALT AND RHODIUM CATALYZED HYDROFORMYLATION OF BUTENE

被引：2

作者：

JOOSTEN, L

MIRBACH, MJ

SAUS, A

机构：

[1] RHEIN WESTFAL TH AACHEN,INST TECH CHEM & PETROLCHEM,MELATENER STR 2,D-5100 AACHEN,FED REP GER

[2] UNIV DUISBURG,FACHBEREICH ANGEW CHEM 6,D-4100 DUISBURG,FED REP GER

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1979年 / 6卷 / 06期

关键词：

D O I：

10.1016/0304-5102(79)80065-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Under the influence of gamma radiation of a Co-60 source the hydroformylation of butene catalyzed by Co2(CO)8 or HRh(CO) (PPh3)3 is enhanced by a factor of ∼4 compared with thermal conditions. Activation energies, product distribution, and reaction order are the same for the thermal and radiation chemical reactions. Therefore it is concluded that both reactions proceed via the same catalytic cycle and that ionizing radiation only leads to a faster entry into this cycle. © 1979.

引用

页码：441 / 447

页数：7

共 18 条

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