PHOTODISSOCIATION DYNAMICS AND EMISSION-SPECTROSCOPY OF H2S IN ITS 1ST ABSORPTION-BAND - A TIME-DEPENDENT QUANTUM-MECHANICAL STUDY

A theoretical study of the photodissociation dynamics of H2S in its first absorption band is presented. The potential energy surfaces underlying the dynamics of the breakup process have been modeled so as to reproduce the principal features of all the available experimental data. The modeling is performed using time dependent quantum dynamical methods and involves the exact numerical solution of the time dependent Schrödinger equation. The fitting of the experimental observations requires the use of potential energy surfaces corresponding to two excited electronic states. We have been able to determine two such surfaces which reproduce the observed structure in the absorption spectrum, the main features of the emission spectrum of the dissociating molecule, and the vibrational distribution of the HS photofragments. The calculations utilize a recently developed method for analyzing the wave packet dynamics to extract the partial photodissociation cross sections. The photodissociation process is found to be consistent with an initial excitation to a single excited dissociative diabatic electronic state which is weakly coupled to another, whose principal role within the first absorption band is to introduce diffuse structure into the absorption spectrum and minor perturbations to the nuclear motion. The motion on the principal dissociative electronic surface is dominated by that in the two bond stretching coordinates, while that on the surface of the second perturbing state is a one dimensional vibrational motion which may correspond to either symmetric stretching or bending, but is most probably a complex combination of both. A new method is presented for performing the time dependent quantum mechanical calculation on two coupled potential energy surfaces when the motions on both surfaces are treated in a reduced dimensionality and the dynamically active coordinates on the two surfaces are different. © 1990 American Institute of Physics.