SYNTHESIS, SOME REACTIONS, AND MOLECULAR-STRUCTURE OF THE PD(BF4)2 COMPLEX OF 1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE

被引：66

作者：

SATO, M ^{[1
]}

SHIGETA, H ^{[1
]}

SEKINO, M ^{[1
]}

AKABORI, S ^{[1
]}

机构：

[1] TOHO UNIV,FAC SCI,DEPT CHEM,FUNABASHI,CHIBA 274,JAPAN

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 458卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80474-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1'-Bis(diphenylphosphino)ferrocene (dppf) reacted with [Pd(CH3CN)4](BF4)2 in the presence of one equivalent of phosphines to give a stable 1/1 complex in which there is a bonding interaction between Fe and Pd atoms. An X-ray structure determination of [(dppf)Pd(PPh3)](BF4)2 confirms the presence of a dative bond (2.877(2) angstrom). In the case of ligands other than phosphines, no complex with a metal-metal bond was obtained.

引用

页码：199 / 204

页数：6

共 32 条

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