ASYMMETRIC EPOXIDATION AND KINETIC RESOLUTION OF ALLYLIC PHOSPHINE OXIDES

被引：20

作者：

CLAYDEN, J ^{[1
]}

WARREN, S ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 19期

关键词：

D O I：

10.1039/p19940002811

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

a diphenylphosphinoyl group undergo asymmetric epoxidation with excellent enantioselectivity, and can undergo kinetic resolution with good diastereoselectivity, with the diphenylphosphinoyl group exerting an anti-directing effect on the epoxidation.

引用

页码：2811 / 2823

页数：13

共 31 条

[1] TRANSPOSITION OF ALLYLIC ALCOHOLS CONTROLLED BY THE PH2PO GROUP - REAGENTS FOR ALPHA-HYDROXY-DIENE SYNTHESIS BY THE HORNER-WITTIG REACTION
BROWN, PS
MCELROY, AB
WARREN, S
[J]. TETRAHEDRON LETTERS, 1985, 26 (02) : 249 - 252
[2] THE SYNTHESIS OF (Z)-PENTA-2,4-DIEN-1-OL AND SUBSTITUTED (E)-PENTADIENOLS BY THE STEREOCHEMICALLY CONTROLLED HORNER-WITTIG REACTION
BROWN, PS
GREEVES, N
MCELROY, AB
WARREN, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (06): : 1485 - 1492
[3] ASYMMETRIC EPOXIDATIONS AND KINETIC RESOLUTIONS OF DELTA-HYDROXY ALLYLIC PHOSPHINE OXIDES
CLAYDEN, J
COLLINGTON, EW
WARREN, S
[J]. TETRAHEDRON LETTERS, 1992, 33 (46) : 7043 - 7046
[4] STEREOCONTROLLED SYNTHESIS OF R OR S, E OR Z UNSATURATED ALPHA-AMINO-ACIDS BY ENANTIOSELECTIVE AND DIASTEREOSELECTIVE EPOXIDATION OF DELTA-HYDROXY ALLYLIC PHOSPHINE OXIDES
CLAYDEN, J
COLLINGTON, EW
WARREN, S
[J]. TETRAHEDRON LETTERS, 1993, 34 (08) : 1327 - 1330
[5] ALKENYL OXAZOLIDINONES BY STEREOSELECTIVE EPOXIDATION OF DELTA-HYDROXY ALLYLIC PHOSPHINE OXIDES - SYNTHESIS OF ANY ISOMER (RR, RS, SR OR SS, E OR Z) BEARING 1,4-RELATED CHIRAL CENTERS ACROSS A DOUBLE-BOND
CLAYDEN, J
COLLINGTON, EW
LAMONT, RB
WARREN, S
[J]. TETRAHEDRON LETTERS, 1993, 34 (13) : 2203 - 2206
[6] THE SYNTHESIS OF DELTA-HYDROXY ALLYLIC PHOSPHINE OXIDES BY PALLADIUM(II)-CATALYZED ALLYLIC ACETATE TRANSPOSITION
CLAYDEN, J
WARREN, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (23): : 2913 - 2923
[7] STEREOCHEMICAL CONTROL (E/Z AND SYN ANTI) BY THE DIPHENYLPHOSPHINOYL GROUP IN THE SYNTHESIS OF ALLYLIC ALCOHOLS BY ALLYLIC REARRANGEMENT AND BY 1,4-DIASTEREOSELECTIVE REDUCTION OF ENONES
CLAYDEN, J
COLLINGTON, EW
ELLIOTT, J
MARTIN, SJ
MCELROY, AB
WARREN, S
WATERSON, D
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1993, (16): : 1849 - 1859
[8] THE SYNTHESIS OF DELTA-HYDROXY ALLYLIC PHOSPHINE OXIDES BY PALLADIUM(II)-CATALYZED ALLYLIC TRANSPOSITION
CLAYDEN, J
COLLINGTON, EW
WARREN, S
[J]. TETRAHEDRON LETTERS, 1992, 33 (46) : 7039 - 7042
[9] CLAYDEN J, 1994, IN PRESS J CHEM SOC, P1529
[10] Clayden J., UNPUB

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