SEPARATION OF O AND P CHLORONITROBENZENES THROUGH HYDROTROPY

被引：19

作者：

GEETHA, KK

TAVARE, NS

GAIKAR, VG

机构：

[1] Department of Chemical Engineering, University of Manchester Institute of Science and Technology

来源：

CHEMICAL ENGINEERING COMMUNICATIONS | 1991年 / 102卷

关键词：

CHLORONITROBENZENES; HYDROTROPY; SEPARATION;

D O I：

10.1080/00986449108910857

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Hydrotropic solutions can be used in separation of two isomers as hydrotropes at high concentrations can enhance solubilities of these isomers in aqueous solution differently. Solubility data are determined for o and p chloronitrobenzenes (CNBs) in aqueous solutions of sodium butyl monoglycol sulphate (NaBMGS). o CNB is highly solubilized as compared to p CNB and can be precipitated out selectively on dilution with water at a reasonable recovery. Precipitation kinetics of p CNB determined from a solvent capacity varying batch crystallizer using the method of s plane analysis show that the relative order with respect to linear growth rate in conventional power law relative nucleation correlation is near unity. © 1991, Taylor & Francis Group, LLC. All rights reserved.

引用

页码：211 / 224

页数：14