THE TIME-RESOLVED RESPONSE OF SEMICONDUCTOR-ELECTROLYTE INTERFACES TO SHORT PULSES OF ILLUMINATION

被引:28
作者
GOTTESFELD, S
机构
[1] Los Alamos Natl Lab, Los Alamos, NM,, USA, Los Alamos Natl Lab, Los Alamos, NM, USA
来源
BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 1987年 / 91卷 / 04期
关键词
ELECTROLYTES - Surfaces - Photoelectricity - PHOTOLUMINESCENCE - Measurements - Relaxation processes;
D O I
10.1002/bbpc.19870910425
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The kinetics of elementary steps in the overall process of photoelectrochemical current generation at an illuminated semiconductor-electrolyte interface can be investigated using relaxation techniques based on perturbation by pulses of illumination. This article reviews theoretical predictions for the form of transients expected under various experimental conditions, and compares these predictions with experimental results. Photopotential, photocurrent, and photoluminescence transient measurements following such perturbations of the semiconductor/electrolyte interface are described.
引用
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页码:362 / 369
页数:8
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