REACTION OF O(1D2) WITH PROPYLENE

被引：17

作者：

KAJIMOTO, O

YAMASAKI, H

FUENO, T

机构：

[1] Department of Chemistry, Faculty of Engineering Science, Osaka University, Toyonaka, Osaka

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 68卷 / 01期

关键词：

D O I：

10.1016/0009-2614(79)80083-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of excited oxygen atom, O(1D2), with propylene has been studied under helium pressure up to 150 atm. The identified oxides and their limiting fractional yields are as follows: propylene oxide 0.22, propionaldehyde 0.22, acetone 0.11, allylalcohol 0.20, acrolein 0.02 and acetaldehyde 0.06. The mechanism of primary attack of O(1D2) on olefin is inferred on the basis of these figures. © 1979.

引用

收藏

页码：127 / 130

页数：4

相关论文

共 11 条

[1] PHOTOCHEMICAL STUDIES .52. THE NITROUS OXIDE-ETHANE SYSTEM [J].

CASTELLION, GA ;

NOYES, WA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (02) :290-293

[2]

Cvetanovic R. J, 1963, ADV PHOTOCHEM, V1, P115

[3] MOLECULAR REARRANGEMENTS IN THE REACTIONS OF OXYGEN ATOMS WITH OLEFINS [J].

CVETANOVIC, RJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1958, 36 (04) :623-634

[4] UNIMOLECULAR REACTIONS OF CHEMICALLY ACTIVATED SPECIES PRODUCED IN SYSTEMS OF METHYLENE WITH PROPENE BUTENE-1,3,3,3-TRIFLUOROPROPENE AND 4,4,4-TRIFLUOROBUTENE-1 [J].

DORER, FH ;

RABINOVI.BS .

JOURNAL OF PHYSICAL CHEMISTRY, 1965, 69 (06) :1964-&

[5]

GUNNING HE, 1966, ADV PHOTOCHEM, V4, P143

[6] FORMATION OF NITROUS-OXIDE IN REACTION OF O(1D2) ATOMS WITH NITROGEN [J].

KAJIMOTO, O ;

CVETANOVIC, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1976, 64 (03) :1005-1015

[7] RELATIVE RATE CONSTANTS OF O(1D2)-OLEFIN REACTIONS [J].

KAJIMOTO, O ;

FUENO, T .

CHEMICAL PHYSICS LETTERS, 1979, 64 (03) :445-447

[8] REACTION OF EXCITED OXYGEN ATOMS O(1D2) WITH NEOPENTANE [J].

PARASKEVOPOULOS, G ;

CVETANOVIC, RJ .

JOURNAL OF CHEMICAL PHYSICS, 1970, 52 (11) :5821-+

[9]

PRESTON KF, 1968, BERICH BUNSEN GESELL, V72, P177

[10] PHOTOOXIDATION OF BUTENE-1 AND ISOBUTENE BY NITROGEN DIOXIDE [J].

SATO, S ;

CVETANOVIC, RJ .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1958, 36 (06) :970-978