COORDINATION CHEMISTRY OF MIXED PYRIDINE PHENOL LIGANDS - THE CRYSTAL-STRUCTURE OF [(NIL(HL))2][PF6]2.0.5MECN.0.5ET2O [HL=6-(2-HYDROXYPHENYL)-2,2'-BIPYRIDINE]

被引：18

作者：

JEFFERY, JC ^{[1
]}

WARD, MD ^{[1
]}

机构：

[1] SCH CHEM,CANTOCKS CLOSE,BRISTOL BS8 1TS,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1992年 / 13期

关键词：

D O I：

10.1039/dt9920002119

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of [{NiL(HL)}2][PF6]2.0.5MeCN.0.5Et2O [HL = 6-(2-hydroxyphenyl)-2,2'-bipyridine] shows that the near-octahedral NiL2 Units, with cis-N4O2 geometries, are associated into dimers via strong hydrogen bonding between the phenolate oxygen atoms of two NiL(HL) units; the proximity of the monomer units in the dimer results in an inter-ligand stacking interaction between parallel aromatic rings.

引用

页码：2119 / 2120

页数：2

共 35 条

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