Poly(pyrazol-1-ylmethyl)benzenes: New multidentate ligands

被引：78

作者：

Hartshorn, CM ^{[1
]}

Steel, PJ ^{[1
]}

机构：

[1] UNIV CANTERBURY,DEPT CHEM,CHRISTCHURCH 1,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1995年 / 48卷 / 09期

关键词：

D O I：

10.1071/CH9951587

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Twelve new multidentate poly(pyrazol-1-ylmethyl)benzene ligands, (5)-(16), have been synthesized by phase-transfer-catalysed alkylations of pyrazoles with poly(bromomethyl) benzenes, and their H-1 and C-13 n.m.r. spectra have been fully assigned. X-Ray crystal structure determinations have been carried out on the tetrachloropalladate salt of the diprotonated form of 1,4-bis(3,5-dimethylpyrazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene and on hexakis(pyrazol-1-ylmethyl)benzene.

引用

页码：1587 / 1599

页数：13

共 57 条

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