CHEMISTRY WITHIN A UNIMOLECULAR MICELLE PRECURSOR - BORON SUPERCLUSTERS BY SITE-SPECIFIC AND DEPTH-SPECIFIC TRANSFORMATIONS OF DENDRIMERS .37. CHEMISTRY OF MICELLES

被引：126

作者：

NEWKOME, GR ^{[1
]}

MOOREFIELD, CN ^{[1
]}

KEITH, JM ^{[1
]}

BAKER, GR ^{[1
]}

ESCAMILLA, GH ^{[1
]}

机构：

[1] TAMPA BAY RES CORP,TAMPA,FL

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1994年 / 33卷 / 06期

关键词：

D O I：

10.1002/anie.199406661

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The water‐soluble dendrimer 1, functionalized at specific internal sites with twelve carborane units, and a dendrimer containing four carborane units in its first generation were generated from dendrimers containing twelve and four internal alkyne functions. This represents the first example of the modification of the interior of a dendrimer at a defined distance from its surface. Water‐soluble forms of boron are important in cancer therapy and in catalysis. R = CH2OCH2C6H5, CH2OH, CH2OSO3H. (Figure Presented.) Copyright © 1994 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：666 / 668

页数：3