STRUCTURE OF [FEH(N2)((H5C2)2PCH2CH2P(C2H5)2)2]BPH4

被引：26

作者：

BUYS, IE

FIELD, LD

HAMBLEY, TW

MCQUEEN, AED

机构：

[1] UNIV SYDNEY, DEPT INORGAN CHEM, SYDNEY, NSW 2006, AUSTRALIA

[2] UNIV SYDNEY, DEPT ORGAN CHEM, SYDNEY, NSW 2006, AUSTRALIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193000903

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis[1,2-bis(diethylphosphino)ethane-P,P']-hydrido(dinitrogen-N)iron(II) tetraphenylborate, [FeH(N2)(C10H24P2)2](C24H20B), M(r) = 816.6, mono-clinic P2(1)/n, a = 16.493 (3), b = 13.691 (4), c = 21.422 (8) angstrom, beta = 111.20 (2)degrees, V = 4509.8 angstrom3, Z = 4, D(x) = 1.203 Mg m-3, lambda(Mo Kalpha) = 0.7107 angstrom, mu=0.503 mm-1, F(000)) = 1752, T = 293 K, R = 0.0651 for 5651 independent observed reflections. The title compound was prepared in 86% yield from [FeHCl{(H5C2)2PCH2CH2P(C2H5)2}2] and NaBPh4 in methanol under an atmosphere of nitrogen. The molecule consists of hydride trans to 'end-bound' molecular nitrogen and two bisphosphine ligands in a pseudo-octahedral arrangement about the iron centre.

引用

页码：1056 / 1059

页数：4

共 15 条

[1]

[Anonymous], 1986, SHELXS86 PROGRAM SOL

[2] A NEW ROUTE TO MOLECULAR NITROGEN COMPLEXES [J].