STUDY OF THERMAL EFFECTS OBSERVED BY DIFFERENTIAL THERMAL ANALYSIS - THEORY AND ITS APPLICATION TO INFLUENCE OF SAMPLE PARAMETERS ON A TYPICAL DTA CURVE

被引：46

作者：

MELLING, R

WILBURN, FW

MCINTOSH, RM

机构：

[1] R & D Laboratories, Pilkington Brothers Limited, Lathom, Ormskirk, Lancashire

来源：

ANALYTICAL CHEMISTRY | 1969年 / 41卷 / 10期

关键词：

D O I：

10.1021/ac60279a009

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A mathematical model has been developed in order to study the effects of sample and block parameters on the transfer of heat in a DTA apparatus. The model is used to investigate the effect of differing sample radius and physical properties on the area, shape, and peak temperature of a typical DTA peak. In this paper, it is assumed that the block has an infinite conductivity and the periphery of the sample is heated so as to rise in temperature at a linear rate. The influence of heat leakage along the thermocouple wires is also studied. © 1969, American Chemical Society. All rights reserved.

引用

页码：1275 / &

共 25 条

[11]

GARN PD, 1965, THERMOANALYTICAL MET

[12]

KISSINGER HE, 1957, ANAL CHEM, V29, P1702, DOI DOI 10.1021/AC60131A045

[13]

Murray P., 1955, BRIT CERAM T, V54, P204

[14] APPLICABILITY OF DU PONT 900 DTA APPARATUS IN QUANTITATIVE DIFFERENTIAL THERMAL ANALYSIS [J].

PACOR, P .

ANALYTICA CHIMICA ACTA, 1967, 37 (02) :200-&

[15] THERMAL DECOMPOSITION OF SOME OXALATES [J].

PADMANABHAN, VM ;

SARAIYA, SC ;

SUNDARAM, AK .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1960, 12 (3-4) :356-359

[16]

PILOYAN GO, 1967, RUSS J INORG CHEM, V12, P313

[17] DIFFERENTIAL THERMAL ANALYSIS AND REACTION KINETICS [J].

REED, RL ;

WEBER, L ;

GOTTFRIE.BS .

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1965, 4 (01) :38-&

[18] KINETIC PARAMETERS FROM DTA TRACES [J].

REICH, L .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1966, 28 (05) :1329-&

[19]

SEWELL EC, 1957, DTA CLAYS, pCH2

[20] NUMERICAL DATA FOR SOME COMMONLY USED SOLID STATE REACTION EQUATIONS [J].

SHARP, JH ;

BRINDLEY, GW ;

ACHAR, BNN .

JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1966, 49 (07) :379-&

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