POLYMERIC DICARBONYL RUTHENIUM(I) ACETATE - AN EFFICIENT CATALYST FOR ALKENE CYCLOPROPANATION WITH DIAZOACETATES

被引：60

作者：

MAAS, G

WERLE, T

ALT, M

MAYER, D

机构：

[1] Fachbereich Chemie, Universität Kaiserslautern, D-6750 Kaiserslautern, Erwin-Schrödinger-Straße

来源：

TETRAHEDRON | 1993年 / 49卷 / 04期

关键词：

D O I：

10.1016/S0040-4020(01)80330-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The polymeric complex [Ru2(CO)4(mu-OAc)2]n is the first Ru(I) catalyst that efficiently catalyzes cyclopropanation of alkenes with diazoacetic esters. The related dinuclear catalyst Ru2(CO)4(mu-OAc)2(MeCN)2 shows a similar performance only for cyclopropanation of monosubstituted alkenes.

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页码：881 / 888

页数：8

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