A SHORT, HIGH-YIELD, STEREOSELECTIVE SYNTHESIS OF RACEMIC EXO-BREVICOMIN AND ENDO-BREVICOMIN

被引：8

作者：

JUN, JG

SHIN, DG

机构：

[1] Department of Chemistry, Hallym University

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 04期

关键词：

D O I：

10.1039/p19910000956

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Stereoselective reduction and cyclization of 6-methyl-2-propionyl-2,3-dihydro-4H-pyran provides brevicomin in quantitative yield as a 86:14 or a 17:83 mixture of exo and endo isomers through DIBAH reduction in ether at reflux or Zn(BH4)2 in the presence of ZnCl2 in ether at 0-degrees-C, respectively.

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页码：956 / 956

页数：1

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