FORMATION OF THE ACTIVE COMPONENT OF A VANADIUM-MOLYBDENUM OXIDE CATALYST IN ACROLEIN OXIDATION

被引：39

作者：

KUZNETSOVA, TG

BORESKOV, GK

ANDRUSHKEVICH, TV

PLYASOVA, LM

MAKSIMOV, NG

OLENKOVA, IP

机构：

[1] Institute of Catalysis, Novosibirsk

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1979年 / 12卷 / 04期

关键词：

D O I：

10.1007/BF02061767

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

An acrolein-containing reaction mixture reduces V5+ to V4+, accompanied by decomposition of the ammonium salt of vanadium-molybdenum-silicon heteropolyacid (HPA) to form a compound with the tentative composition of VMo3O11+x, which is the active component of the catalyst. © 1979 Akadémiai Kiadó.

引用

页码：531 / 536

页数：6

共 10 条

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KUZNETSOVA, GG ;

BONDAREVA, VM ;

GORSHKOVA, TP ;

OLENKOVA, IP ;

LEBEDEVA, NI .

REACTION KINETICS AND CATALYSIS LETTERS, 1979, 12 (04) :463-467

[2]

BIELANSKI A, 1974, B ACAD POL SCI-CHIM, V22, P773

[3]

BOCHAROVA TI, 1978, IZV SIB OTD AKAD KN, V6, P104

[4]

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[5]

Kitahara M., 1967, KOGYO KAGAKU ZASSHI, V70, P895

[6]

PLYASOVA LM, 1978, STUDIES PROPERTIES A, P74

[7] ESR INVESTIGATION OF VANADIUM-MOLYBDENUM OXIDE CATALYSTS [J].

SELYUTIN, GE ;

MAKSIMOV, NG ;

ZENKOVETS, GA ;

TARASOVA, DV ;

ANUFRIENKO, VF .

REACTION KINETICS AND CATALYSIS LETTERS, 1979, 10 (01) :25-29

[8]

1887, Patent No. 356772

[9]

1960, ASTM50508 XRAY POWD

[10]

6809045

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