GENERATION OF ALLYLIC AND RELATED ORGANOZIRCONIUMS THROUGH A HIGHLY EFFECTIVE ZIRCONIUM-BETA-ALKOXIDE ELIMINATION-REACTION

被引：55

作者：

ITO, H ^{[1
]}

NAKAMURA, T ^{[1
]}

TAGUCHI, T ^{[1
]}

HANZAWA, Y ^{[1
]}

机构：

[1] TOKYO COLL PHARM, HACHIOJI, TOKYO 19203, JAPAN

来源：

TETRAHEDRON | 1995年 / 51卷 / 15期

关键词：

D O I：

10.1016/0040-4020(94)01137-O

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Reactions and characterization of allylic and related zirconium reagents (allenic and gamma-alkoxyallylic zirconiums) generated by treatment of allylic and/or propargylic ethers with a zirconocene-butene complex (''Cp(2)Zr'') are described.

引用

页码：4507 / 4518

页数：12

共 74 条

[1] [Anonymous], 1981, SYNTHESIS ACETYLENES
[2] BIELLMANN JF, 1982, ORG REACTIONS, V27, P1
[3] GROUP-4 METAL-COMPLEXES OF BENZYNES, CYCLOALKYNES, ACYCLIC ALKYNES, AND ALKENES
BUCHWALD, SL
NIELSEN, RB
[J]. CHEMICAL REVIEWS, 1988, 88 (07) : 1047 - 1058
[4] SYNTHESIS, STRUCTURE, AND REACTIONS OF (1-ETHOXYETHYL)ZIRCONOCENE CHLORIDE, A STABLE ACYCLIC SECONDARY ZIRCONOCENE ALKYL
BUCHWALD, SL
NIELSEN, RB
DEWAN, JC
[J]. ORGANOMETALLICS, 1988, 7 (11) : 2324 - 2328
[5] BUCHWALD SL, 1989, CHEM SCRIPTA, V29, P417
[6] CHINO M, 1994, SYNLETT, P359
[7] THE STEREOCHEMICAL ASSIGNMENT OF THE 1,2-DIPHENYLBUT-3-EN-1-OLS, (1RS,2RS,3RS)-3,4-EPOXY-1,2-DIPHENYLBUTAN-1-OL AND (1RS,2RS,3SR)-3,4-EPOXY-1,2-DIPHENYLBUTAN-1-OL AND (2RS,3SR)-3,4-EPOXY-1,2-DIPHENYLBUTAN-1-ONE AND (2RS,3RS)-3,4-EPOXY-1,2-DIPHENYLBUTAN-1-ONE AND CRYSTAL-STRUCTURE OF (1RS,2RS,3RS)-3,4-EPOXY-1,2-DIPHENYLBUTAN-1-OL-O
COXON, JM
SIMPSON, GW
STEEL, PJ
TRENERRY, VC
[J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1984, 37 (01) : 65 - 72
[8] RING-OPENING REACTIONS OF CYCLIC ALLYLIC ETHERS BY ZIRCONOCENE COMPLEXES OF CYCLIC ALKYNES
CUNY, GD
BUCHWALD, SL
[J]. ORGANOMETALLICS, 1991, 10 (01) : 363 - 365
[9] Epsztein R., 1984, COMPREHENSIVE CARBAN, P107
[10] CPZR(ALLYL)3 - THE MOLECULAR-STRUCTURE OF A PI-DYNAMIC AND SIGMA-DYNAMIC ALLYL TRANSITION-METAL COMPLEX
ERKER, G
BERG, K
ANGERMUND, K
KRUGER, C
[J]. ORGANOMETALLICS, 1987, 6 (12) : 2620 - 2621

← 1 2 3 4 5 6 7 8 →