GENERATION OF ALLYLIC AND RELATED ORGANOZIRCONIUMS THROUGH A HIGHLY EFFECTIVE ZIRCONIUM-BETA-ALKOXIDE ELIMINATION-REACTION

被引:55
作者
ITO, H [1 ]
NAKAMURA, T [1 ]
TAGUCHI, T [1 ]
HANZAWA, Y [1 ]
机构
[1] TOKYO COLL PHARM, HACHIOJI, TOKYO 19203, JAPAN
关键词
D O I
10.1016/0040-4020(94)01137-O
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reactions and characterization of allylic and related zirconium reagents (allenic and gamma-alkoxyallylic zirconiums) generated by treatment of allylic and/or propargylic ethers with a zirconocene-butene complex (''Cp(2)Zr'') are described.
引用
收藏
页码:4507 / 4518
页数:12
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