THE INVENTION OF RADICAL REACTIONS .34. HOMOLOGATION OF CARBOXYLIC-ACIDS TO ALPHA-KETO CARBOXYLIC-ACIDS BY BARTON-ESTER BASED RADICAL-CHAIN CHEMISTRY

被引：36

作者：

BARTON, DHR ^{[1
]}

CHERN, CY ^{[1
]}

JASZBERENYI, JC ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

TETRAHEDRON | 1995年 / 51卷 / 07期

关键词：

D O I：

10.1016/0040-4020(94)01054-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carboxylic acids can be transformed into the homologous alpha-keto acids by Barton-ester based radical chemistry. This method was especially successful when ethyl alpha-trifluoroacetoxy acrylate was used as a radical trap.

引用

页码：1867 / 1886

页数：20

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