THE INVENTION OF RADICAL REACTIONS .34. HOMOLOGATION OF CARBOXYLIC-ACIDS TO ALPHA-KETO CARBOXYLIC-ACIDS BY BARTON-ESTER BASED RADICAL-CHAIN CHEMISTRY

被引：36

作者：

BARTON, DHR ^{[1
]}

CHERN, CY ^{[1
]}

JASZBERENYI, JC ^{[1
]}

机构：

[1] TEXAS A&M UNIV,DEPT CHEM,COLLEGE STN,TX 77843

来源：

TETRAHEDRON | 1995年 / 51卷 / 07期

关键词：

D O I：

10.1016/0040-4020(94)01054-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Carboxylic acids can be transformed into the homologous alpha-keto acids by Barton-ester based radical chemistry. This method was especially successful when ethyl alpha-trifluoroacetoxy acrylate was used as a radical trap.

引用

页码：1867 / 1886

页数：20

共 107 条

[81]

Nelson R. B., 1973, ORG PREP PROCED INT, V5, P55

[82] The metabolism of lysine [J].

Neuberger, A ;

Sanger, F .

BIOCHEMICAL JOURNAL, 1944, 38 :119-125

[83]

NIZNIK GE, 1974, J ORG CHEM, V39, P600, DOI 10.1021/jo00919a004

[84]

OSBORN MJ, 1960, P NATL ACAD SCI USA, V50, P499

[85]

PAGE PCB, 1986, TETRAHEDRON LETT, V27, P1947

[86] EPOXIDATION OF DIETHYL ETHYLIDENEMALONATE BY ALKALINE HYDROGEN PEROXIDE [J].

PAYNE, GB .

JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (12) :2048-2049

[87]

POTIER P, 1978, REV LATINOAMER QUIM, V9, P47

[88] On phenyl sulfoxy-acetic acid. (II.) [J].

Pummerer, R .

BERICHTE DER DEUTSCHEN CHEMISCHEN GESELLSCHAFT, 1910, 43 :1401-1412

[89]

Pummerer R., 1909, CHEM BER, V42, P2282, DOI DOI 10.1002/CBER.190904202125

[90] DIOXOLANONES AS SYNTHETIC INTERMEDIATES .1. SYNTHESIS OF ALPHA-KETO ACIDS, ALPHA-KETO ALDEHYDES, AND ALPHA-KETOLS [J].

RAMAGE, R ;

GRIFFITHS, GJ ;

SHUTT, FE ;

SWEENEY, JNA .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1984, (07) :1531-1537

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