共 21 条
[21]
WOLFROM ML, 1962, ADVANCES CARBOHYD ED, V17, P142
COUMARINS .6. A REVISED STRUCTURE OF COLUMBIANIN AND PERTINENT MASS SPECTRAL STUDIES
被引：19
作者：
SHIPCHANDLER, M
SOINE, TO
机构：
[1] Department of Medicinal Chemistry, College of Pharmacy, University of Minnesota, Minneapolis, Minnesota
基金：
美国国家卫生研究院;
关键词：
Columbianin structure—revised;
Column chromatography—separation;
Coumarins;
IR spectrophotometry—structure;
Mass spectrometry—structure;
NMR spectrometry—identity;
Paper chromatography—identity;
Polarimetry—identity;
TLC—identity;
D O I：
10.1002/jps.2600570505
中图分类号：
R914 [药物化学];
学科分类号：
100701 ;
摘要：
The previous erroneous assignment of the structure of columbianin as a D‐glucoside of columbianetin has been revised to indicate that it is a β‐D‐gentiobioside. The mass spectral characteristics of columbianin, its acetate, the true β‐D‐gluco‐pyranoside of columbianetin, and its acetate have been examined and probable fragmentation pathways proposed. Copyright © 1968 Wiley‐Liss, Inc., A Wiley Company
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页码：747 / +
页数：1
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