AMIDOBIS(PENTAMETHYLCYCLOPENTADIENYL)TITANIUM(III)

被引：19

作者：

BRADY, E ^{[1
]}

TELFORD, JR ^{[1
]}

MITCHELL, G ^{[1
]}

LUKENS, W ^{[1
]}

机构：

[1] UNIV CALIF BERKELEY,LAWRENCE BERKELEY LAB,DIV CHEM SCI,BERKELEY,CA 94720

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194005792

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Ti(NH2)(Me(5)C(5))(2)] (I), is a bent metallocene with the NH2 group oriented so as to maximize the pi interaction between the N and Ti atoms. The Ti-N bond length is short [1.944 (2) Angstrom], consistent with increased pi bonding.

引用

页码：558 / 560

页数：3

共 7 条

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[2]

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[4] SYNTHESIS AND MOLECULAR-STRUCTURE OF (ETA-5-C5ME5)2HF(H)(NHME) - STRUCTURAL EVIDENCE FOR NITROGEN-TO-HAFNIUM PI-DONATION [J].

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BERCAW, JE .

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[5]

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[6]

STOUT GH, 1968, XRAY STRUCTURE DETER, P412

[7] AN EMPIRICAL-METHOD FOR CORRECTING DIFFRACTOMETER DATA FOR ABSORPTION EFFECTS [J].

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STUART, D .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (JAN) :158-166

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