INFINITE-DILUTION ACTIVITY-COEFFICIENTS BY COMPARATIVE EBULLIOMETRY - MEASUREMENTS AND GROUP-CONTRIBUTION CALCULATIONS FOR SOME BINARY-MIXTURES ETHER PLUS N-ALKANE AND ETHER PLUS ALCOHOL

被引：17

作者：

DELCROS, S ^{[1
]}

GROLIER, JPE ^{[1
]}

DOHNAL, V ^{[1
]}

FENCLOVA, D ^{[1
]}

机构：

[1] PRAGUE INST CHEM TECHNOL,DEPT PHYS CHEM,CR-16628 PRAGUE,CZECH REPUBLIC

来源：

CHEMICAL ENGINEERING SCIENCE | 1995年 / 50卷 / 18期

关键词：

D O I：

10.1016/0009-2509(95)00137-T

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Infinite-dilution activity coefficients gamma(i)(infinity) were measured for 33 solute-solvent pairs of the type ether + n-alkane and ether + alcohol using the comparative ebulliometry technique. The experimental results were compared with the values obtained by two group contribution models, DISQUAC and modified UNIFAC (Dortmund).

引用

页码：2957 / 2962

页数：6

共 22 条

[1]

Boublik T., 1984, VAPOUR PRESSURES PUR

[2] VAPOR-PRESSURES, REFRACTIVE-INDEXES, AND DENSITIES AT 20.0-DEGREES-C, AND VAPOR LIQUID EQUILIBRIUM AT 101.325 KPA, IN THE TERT-AMYL METHYL-ETHER METHANOL SYSTEM [J].

CERVENKOVA, I ;

BOUBLIK, T .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1984, 29 (04) :425-427

[3]

DELCROS S, 1995, IN PRESS DISQUAC CAL

[4] INFINITE-DILUTION ACTIVITY-COEFFICIENTS BY COMPARATIVE EBULLIOMETRY - BINARY-SYSTEMS OF CHLOROMETHANES, CHLOROETHANES AND FREON-113 [J].

DOHNAL, V ;

VRBKA, P .

FLUID PHASE EQUILIBRIA, 1990, 54 :121-131

[5] INFINITE-DILUTION ACTIVITY-COEFFICIENTS BY COMPARATIVE EBULLIOMETRY - A MODEL OF EBULLIOMETER AND THE EXPERIMENTAL EQUIPMENT AND PROCEDURE [J].

DOHNAL, V ;

NOVOTNA, M .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1986, 51 (07) :1393-1402

[6] INFINITE-DILUTION ACTIVITY-COEFFICIENTS BY COMPARATIVE EBULLIOMETRY - THE MIXTURES OF FREON-112 WITH OXYGENATED SOLVENTS AND HYDROCARBONS [J].

DOHNAL, V ;

NOVOTNA, M .

FLUID PHASE EQUILIBRIA, 1985, 23 (2-3) :303-313

[7]

DYKYJ J, 1984, VAPOR PRESSURES ORGA

[8]

DYKYJ J, 1979, VAPOR PRESSURES ORGA

[9] LIMITING ACTIVITY-COEFFICIENTS FOR (1,1,2-TRICHLOROTRIFLUOROETHANE (FREON-113) + AN OXYGEN-CONTAINING SUBSTANCE OR A HYDROCARBON) [J].

FENCLOVA, D ;

DOHNAL, V .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1993, 25 (05) :615-619

[10]

Fredenslund A., 1977, VAPOR LIQUID EQUILIB, V1st

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