HIGH-RESOLUTION HETERONUCLEAR NMR-SPECTROSCOPY IN AN INHOMOGENEOUS MAGNETIC-FIELD

被引：7

作者：

DUCE, SL

HALL, LD

NORWOOD, TJ

机构：

[1] Herchel Smith Laboratory for Medicinal Chemistry, Cambridge University School of Clinical Medicine, Cambridge, CB2 2PZ England, Forvie Site, Robinson Way

来源：

JOURNAL OF MAGNETIC RESONANCE | 1990年 / 89卷 / 02期

关键词：

D O I：

10.1016/0022-2364(90)90234-Z

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A family of five related pulse sequences is described, each of which produces a high-resolution 1H13C heteronuclear spectrum from an inhomogeneous magnetic field. All are based upon observation of a single-quantum coherence-transfer echo. The basic pulse sequence was tailored so that the peaks exhibited heteronuclear scalar coupling, homonuclear scalar coupling, or no couplings at all. One pulse sequence produces a spectrum which is remarkably similar, once a frequency scaling is taken into account, to the conventional 1H-decoupled 13C spectrum obtained in a homogeneous magnetic field. Semiquantitative peak integrals can also be recovered from these spectra. © 1990.

引用

页码：273 / 286

页数：14

共 15 条

[11]

MULLER L, 1975, J CHEM PHYS, V63, P5496

[12] 2-DIMENSIONAL SPIN-ECHO CORRELATED SPECTROSCOPY (SECSY) FOR H-1-NMR STUDIES OF BIOLOGICAL MACROMOLECULES [J].

NAGAYAMA, K ;

WUTHRICH, K ;

ERNST, RR .

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS, 1979, 90 (01) :305-311

[13] HIGH-RESOLUTION, ZERO QUANTUM TRANSITION (TWO-DIMENSIONAL) NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY - SPECTRAL-ANALYSIS [J].

POUZARD, G ;

SUKUMAR, S ;

DHALL, L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (14) :4209-4215

[14] HIGH-RESOLUTION NMR-SPECTRA IN INHOMOGENEOUS MAGNETIC-FIELDS - APPLICATION OF TOTAL SPIN COHERENCE TRANSFER ECHOES [J].

WEITEKAMP, DP ;

GARBOW, JR ;

MURDOCH, JB ;

PINES, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (12) :3578-3579

[15] SELECTIVE DETECTION OF MULTIPLE QUANTUM TRANSITIONS IN NMR BY 2-DIMENSIONAL SPECTROSCOPY [J].

WOKAUN, A ;

ERNST, RR .

CHEMICAL PHYSICS LETTERS, 1977, 52 (03) :407-412

← 1 2 →