POLYFUNCTIONAL BICYCLO[6.3.0]UNDECANE INTERMEDIATES

被引：7

作者：

CHORLTON, AP ^{[1
]}

MORRIS, GA ^{[1
]}

SUTHERLAND, JK ^{[1
]}

机构：

[1] VICTORIA UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 05期

关键词：

D O I：

10.1039/p19910001205

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

On thermolysis, 2-hydroxy-1-isopropyl-2-vinylbicyclo[4.3.0]non-6-en-8-one 18 undergoes oxy-Cope rearrangement followed by an 'ene' reaction to give 5-hydroxy-11-isopropyl-8-methyltricyclo[6.3.0.0(1,5)]undec-10-ene-9-one 21, which is cleaved by Pb(OAc)4-I2 to 11-isopropyl-8-methylbicyclo[6.3.0]undeca-1,10-diene-5,9-dione 23. Aspects of the chemistry of the dione are explored.

引用

页码：1205 / 1210

页数：6