NOVEL STABLE GERMANIMINES - SYNTHESIS AND CHARACTERIZATION OF DIMESITYLGERMANIMINE DERIVATIVES OF METHYL ANTHRANILATE AND N,N-DIMETHYLANTHRANILAMIDE

被引：17

作者：

RIVIEREBAUDET, M

KHALLAAYOUN, A

SATGE, J

机构：

[1] Laboratoire de Chimie des Organominéraux, URA 477 du CNRS, Université Paul Sabotier, 31062 Toulouse Cedex

来源：

ORGANOMETALLICS | 1993年 / 12卷 / 04期

关键词：

D O I：

10.1021/om00028a008

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The title compounds (2a and 2b) are novel, thermally stable germanimines formed by dehydrohalogenation of the corresponding precursor halogermylamines with tert-butyllithium; each undergoes protic dipolar addition and 1,3-cycloaddition reactions, characteristic of germanium-nitrogen double bonds.

引用

页码：1003 / 1005

页数：3

共 14 条

[1] MULTIPLY BONDED GERMANIUM SPECIES - RECENT DEVELOPMENTS
BARRAU, J
ESCUDIE, J
SATGE, J
[J]. CHEMICAL REVIEWS, 1990, 90 (01) : 283 - 319
[2] ESCUDIE J, IN PRESS COORD CHEM
[3] KHALLAAYOUN A, 1991, MAIN GROUP MET CHEM, V14, P89
[4] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF GERMAIMINES
MELLER, A
OSSIG, G
MARINGGELE, W
STALKE, D
HERBSTIRMER, R
FREITAG, S
SHELDRICK, GM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (16) : 1123 - 1124
[5] 2-GERMYLAZETIDINES - PRECURSORS OF GERMAIMINES
RIVIEREBAUDET, M
RIVIERE, P
SATGE, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 154 (02) : C23 - C27
[6] A SIMPLE GENERAL-METHOD FOR CONVERSION OF FUNCTIONALIZED ESTERS TO FUNCTIONALIZED AMIDES
RIVIEREBAUDET, M
MORERE, A
DIAS, M
[J]. TETRAHEDRON LETTERS, 1992, 33 (43) : 6453 - 6456
[7] N-DIETHYLGERMYL DERIVATIVES OF METHYL 3-AMINO-2-THIOPHOATE
RIVIEREBAUDET, M
MORERE, A
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1991, 62 (1-4): : 211 - 217
[8] N-MESITYLDIMESITYLGERMAIMINE
RIVIEREBAUDET, M
SATGE, J
MORERE, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 386 (01) : C7 - C11
[9] STERICALLY HINDERED GERMANIUM-NITROGEN BOND .2. N-MONOHALOGERMANYL SECONDARY AMINES
RIVIEREBAUDET, M
KHALLAAYOUN, A
SATGE, J
AHRA, M
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1992, 22 (06): : 683 - 701
[10] PREPARATION OF ORGANOCHLOROGERMYLAMINES STABILIZED BY A CHELATING ORGANIC SUBSTITUENT - 3-AMINO-2-METHYLTHIOPHOATE
RIVIEREBAUDET, M
RIVIERE, P
CASTEL, A
MORERE, A
ABDENNHADER, C
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 409 (1-2) : 131 - 141

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