HOMOALLYLIC REARRANGEMENT OF CYCLOPROPYLCARBINYL BORATES - A STEREOSPECIFIC SYNTHESIS OF TRANS-4-ARYL-3-BUTENOLS

被引：5

作者：

BREUER, E

SAREL, S

机构：

[1] Department of Pharmaceutical Chemistry, The Hebrew University School of Pharmacy, Jerusalem

来源：

TETRAHEDRON | 1968年 / 24卷 / 21期

关键词：

D O I：

10.1016/S0040-4020(01)96826-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Thermal decomposition of methyl aryl cyclopropylcarbinyl borates, followed by hydrolysis, gives rise to mixtures of 1-aryl-1-cyclopropylethylene, and of 4-aryl-3-pentenol. Similarly, aryl cyclopropylcarbinylborates yield trans-4-aryl-3-butenols, while dicyclopropyl carbinyl borate gives a mixture of trans- and cis-4-cyclopropyl-3-butenols. © 1968.

引用

页码：6339 / &

共 12 条

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