共 12 条
- [11] STEINBERG H, 1964, ORGANOBORON CHEMISTR, V1, P121
- [12] 1966, 36 M ISR CHEM SOC
HOMOALLYLIC REARRANGEMENT OF CYCLOPROPYLCARBINYL BORATES - A STEREOSPECIFIC SYNTHESIS OF TRANS-4-ARYL-3-BUTENOLS
被引：5
作者：
BREUER, E
SAREL, S
机构：
[1] Department of Pharmaceutical Chemistry, The Hebrew University School of Pharmacy, Jerusalem
来源：
关键词：
D O I：
10.1016/S0040-4020(01)96826-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ;
081704 ;
摘要：
Thermal decomposition of methyl aryl cyclopropylcarbinyl borates, followed by hydrolysis, gives rise to mixtures of 1-aryl-1-cyclopropylethylene, and of 4-aryl-3-pentenol. Similarly, aryl cyclopropylcarbinylborates yield trans-4-aryl-3-butenols, while dicyclopropyl carbinyl borate gives a mixture of trans- and cis-4-cyclopropyl-3-butenols. © 1968.
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页码：6339 / &
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