SYNTHESIS OF A PERACETYLATED STEREOISOMER OF DE-ROSAS CALDITOL - SOME QUESTIONS ABOUT THE CORRECTNESS OF THE ORIGINAL STRUCTURE ASSIGNED TO THIS NATURAL PRODUCT

被引：14

作者：

FAIRBANKS, AJ ^{[1
]}

SINAY, P ^{[1
]}

机构：

[1] ECOLE NORMALE SUPER,CNRS,DEPT CHEM,F-75231 PARIS 05,FRANCE

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 06期

关键词：

1,3-DIOXOLAN-4-ONE; HIGHER CARBON SUGARS; ALDOL CONDENSATION; CALDITOL;

D O I：

10.1016/0040-4039(94)02388-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Comparison of the C-13 nmr spectrum of the nonacetate of a synthetic stereoisomer of calditol with that of the nonacetate of the natural product, combined with a comparison of the C-13 nmr spectrum of the peracetate of a hexitol derived from calditol with all known peracetates of open chain hexitols, invalidates the originally proposed structure.

引用

页码：893 / 896

页数：4

共 15 条

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