SYNTHESIS AND STRUCTURE OF CATIONIC, ETA(3)-ALLENYL/PROPARGYLPALLADIUM COMPLEXES

被引：73

作者：

OGOSHI, S

TSUTSUMI, K

KUROSAWA, H

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期

关键词：

PALLADIUM; ALLENYL; PROPARGYL;

D O I：

10.1016/0022-328X(95)05475-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of eta(1)-allenyl- or eta(1)-propargylpalladium bis(triphenylphosphine) chloride with AgBF4, or NaBPh(4) afforded cationic eta(3)-allenyl/propargylpalladium complexes. The molecular structure and some properties of the eta(3)-allenyl/propargylpalladium were revealed.

引用

收藏

页码：C19 / C21

页数：3

相关论文

共 13 条

[1] ETA-3-BONDING OF PHENYLALLENYL IN A ZIRCONOCENE COMPLEX [J].

BLOSSER, PW ;

GALLUCCI, JC ;

WOJCICKI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (07) :2994-2995

[2] INTERCONVERSION OF ETA(1)-PROPARGYL, ETA(1)-ALLENYL, AND ETA(3)-PROPARGYL ALLENYL LIGANDS ON PLATINUM - SYNTHESIS, STRUCTURE, AND REACTIVITY OF [(PH3P)2PT(ETA(3)-CH2CCPH)]O3SCF3 [J].

BLOSSER, PW ;

SCHIMPFF, DG ;

GALLUCCI, JC ;

WOJCICKI, A .

ORGANOMETALLICS, 1993, 12 (06) :1993-1995

[3] NUCLEOPHILIC-ATTACK AT THE CENTRAL CARBON OF A CATIONIC (ETA-3-PROPARGYL)RHENIUM COMPLEX [J].

CASEY, CP ;

YI, CS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (16) :6597-6598

[4] ALLENYLPALLADIUM(II) SPECIES - POSSIBLE INTERMEDIATES IN THE TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0)-CATALYSED FORMATION OF ALLENES FROM PROP-2-YNYLIC SUBSTRATES [J].

ELSEVIER, CJ ;

KLEIJN, H ;

RUITENBERG, K ;

VERMEER, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (24) :1529-1530

[5] SYNTHESIS, STRUCTURE, AND REACTIVITY OF SOME (OMICRON-ALLENYL)PALLADIUM(II) AND (OMICRON-PROP-2-YNYL)PALLADIUM(II) COMPLEXES [J].

ELSEVIER, CJ ;

KLEIJN, H ;

BOERSMA, J ;

VERMEER, P .

ORGANOMETALLICS, 1986, 5 (04) :716-720

[6] A VERSATILE ROUTE TO THE BETA-SUBSTITUTED PI-ALLYL COMPLEXES VIA ADDITION TO A CATIONIC ETA(3)-PROPARGYL COMPLEX OF PLATINUM [J].

HUANG, TM ;

CHEN, JT ;

LEE, GH ;

WANG, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (03) :1170-1171

[7] A NEW FURAN ANNELATION REACTION BY THE PALLADIUM-CATALYZED REACTION OF 2-ALKYNYL CARBONATES OR 2-(1-ALKYNYL)OXIRANES WITH BETA-KETO-ESTERS [J].

MINAMI, I ;

YUHARA, M ;

WATANABE, H ;

TSUJI, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1987, 334 (1-2) :225-242

[8]

MO VV, 1991, MENDELEEV COMMUN, P103

[9] NUCLEOPHILIC-SUBSTITUTION AT THE CENTRAL ALLYL CARBON-ATOM OF A (PI-ALLYL)PLATINUM COMPLEX [J].

OHE, K ;

MATSUDA, H ;

MORIMOTO, T ;

OGOSHI, S ;

CHATANI, N ;

MURAI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (09) :4125-4126

[10] A NOVEL SYNTHESIS OF (OXODIMETHYLENEMETHANE)-PALLADIUM AND (OXODIMETHYLENEMETHANE)-PLATINUM COMPLEXES [J].

OHSUKA, A ;

FUJIMORI, T ;

HIRAO, T ;

KUROSAWA, H ;

IKEDA, I .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (12) :1039-1040