FORMATION OF [CP2TI(CCSIME3)] FROM TITANOCENE AND 1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE

被引：70

作者：

ROSENTHAL, U ^{[1
]}

GORLS, H ^{[1
]}

机构：

[1] UNIV JENA,MAX PLANCK GESELL,ARBEITSGRP CO2 CHEM,O-6900 JENA,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1992年 / 439卷 / 02期

关键词：

D O I：

10.1016/0022-328X(92)80235-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactions of Cp2TiCl2 with Mg and Me3SiC=C-C=CSiMe3 in THF, and of Cp2Ti(Me3SiC= CSiMe3) with Me3SiC=C=CSiMe3 yield the dinuclear titanium(III) complex [Cp2Ti(C=CSiMe3)]2. During these reactions the central C-C bond of the starting butadiyne is split by the in situ generated titanocene "Cp2Ti".

引用

页码：C36 / C41

页数：6

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