STUDIES ON THE SOLID OBTAINED FROM RADIOLYSIS OF GERMANE METHANE MIXTURES

被引：22

作者：

ANTONIOTTI, P ^{[1
]}

BENZI, P ^{[1
]}

CASTIGLIONI, M ^{[1
]}

OPERTI, L ^{[1
]}

VOLPE, P ^{[1
]}

机构：

[1] UNIV TURIN,DIPARTIMENTO CHIM GEN & ORGAN APPL,CORSO MASSIMO DAZEGLIO 48,I-10125 TURIN,ITALY

来源：

CHEMISTRY OF MATERIALS | 1992年 / 4卷 / 03期

关键词：

D O I：

10.1021/cm00021a040

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Some physicochemical properties of the amorphous material obtained by X-ray radiolysis of GeH4/CH4 mixtures are reported. The C/Ge ratio in the solid is far lower than in the gas-phase reactants. The material does not dissolve in the usual solvents and is thermally stable up to about 440 K. EPR signals attributable to both free electrons and germanium appear in the 525-1175 K temperature range.

引用

页码：717 / 720

页数：4

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