ACTION OF BASE ON CYCLO-OCTATETRAENE 1,2,5,6-TETRABROMOCYCLO-OCTANES AND POLYBROMOCYCLODODECANES

被引：15

作者：

EGLINTON, G

MCCRAE, W

RAPHAEL, RA

ZABKIEWI.JA

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 03期

关键词：

D O I：

10.1039/j39690000474

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The action of potassium t-butoxide in diglyme on trans,anti,trans- and trans,syn,trans-1,2,5,6-tetrabromocyclooctane and on cyclo-octatetraene was found to produce benzocyclobutene, styrene, cyclo-octa-1,3,5-triene, and ethylbenzene. Similar base treatment of 1,2,5,6,9,10-hexabromocyclododecane gave the hitherto unknown 1,2-benzocyclo-octa-1,3,5-triene while 1,2,5,6-tetrabromocyclododecane produced 1,2-benzocyclo-oct-1-ene.

引用

页码：474 / &