(-)-ALPHA-ISOSPARTEINE AS A CHIRAL LIGAND IN ASYMMETRIC ALLYLIC ALKYLATION

被引：63

作者：

KANG, JY

CHO, WO

CHO, HG

机构：

[1] Department of Chemistry, Sogang Umversity, Seoul

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 07期

关键词：

D O I：

10.1016/0957-4166(94)80176-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cationic complex [Pd(pi-Allyl)(Isosparteine)](+) PF6- was found to be a suitable catalyst for asymmetric alkylation of allylic acetates. Asymmetric allylic alkylation with NaCH(CO(2)Me)(2) was carried out in the presence of a 5 mol % of the catalyst to give chiral alkylation products with high enantiomeric excesses.

引用

页码：1347 / 1352

页数：6

共 22 条

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