LANTHANIDE ALKOXIDES .3. 4-COORDINATE ANIONIC NEODYMIUM(III) ALKOXIDES AND AMIDES

被引：64

作者：

EDELMANN, FT

STEINER, A

STALKE, D

GILJE, JW

JAGNER, S

HAKANSSON, M

机构：

[1] UNIV HAWAII MANOA,DEPT CHEM,HONOLULU,HI 96822

[2] CHALMERS UNIV TECHNOL,DEPT INORGAN CHEM,S-41296 GOTHENBURG,SWEDEN

[3] GOTHENBURG UNIV,S-41296 GOTHENBURG,SWEDEN

来源：

POLYHEDRON | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)84729-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Tetracoordinate anionic neodymium(III) alkoxides and amides are obtained by adduct formation of Nd[OC(tBu)3]3 (1) and Nd[N(SiMe3)2]3 (2) with either LiCl or LiOSiMe3. The compounds (THF)3Li(mu-Cl)Nd[OC(tBu)3]3 (3), (THF)3Li(mu-Cl)Nd [N(SiMe3)2]3 (4) and [Li(THF)4][{(Me3Si)2N}3Nd(OSiMe3)] (5) have been characterized by single-crystal X-ray analyses.

引用

页码：539 / 546

页数：8

共 35 条

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