NICKEL-CATALYZED DEHYDROGENATION OF AMINES TO NITRILES

被引：73

作者：

YAMAZAKI, S

YAMAZAKI, Y

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 01期

关键词：

D O I：

10.1246/bcsj.63.301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aliphatic primary amines having α-methylene underwent oxidative dehydrogenation on treatment with NiSO4 as a catalyst and K2S2O8 as an oxidant to give the corresponding nitriles in good yields. Benzhydrylamine was converted to benzhydrylideneamine quantitatively under the same reaction conditions.

引用

页码：301 / 303

页数：3

共 14 条

[1] CATALYSIS - AUTOXIDATION IN PRESENCE OF ACTIVE COBALT OXIDE [J].

BELEW, JS ;

GARZA, C ;

MATHIESO.JW .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (11) :634-&

[2]

CENINI S, 1982, J MOL CATAL, V15, P297, DOI 10.1016/0304-5102(82)80023-0

[3]

CLARKE TG, 1968, TETRAHEDRON LETT, P5685

[4]

FELDHUES U, 1982, SYNTHESIS-STUTTGART, P145

[5] NICKEL PEROXIDE OXIDATION OF ORGANIC COMPOUNDS [J].

GEORGE, MV ;

BALACHANDRAN, KS .

CHEMICAL REVIEWS, 1975, 75 (04) :491-519

[6] OXO COMPLEXES OF RUTHENIUM(VI) AND (VII) AS ORGANIC OXIDANTS [J].

GREEN, G ;

GRIFFITH, WP ;

HOLLINSHEAD, DM ;

LEY, SV ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1984, (04) :681-686

[7]

LEE GA, 1976, TETRAHEDRON LETT, P1641

[8] OXIDATIONS INVOLVING SILVER .9. OXIDATION OF PRIMARY AMINES BY SILVER(II) PICOLINATE [J].

LEE, JB ;

PARKIN, C ;

SHAW, MJ ;

HAMPSON, NA ;

MACDONAL.KI .

TETRAHEDRON, 1973, 29 (05) :751-752

[9]

NAKAGAWA K, 1963, CHEM PHARM BULL, V11, P296

[10] OXIDATION OF AMINES IN THE PRESENCE OF RUTHENIUM COMPLEXES - MOLECULAR-OXYGEN AND IODOSYLBENZENE AS OXIDANTS [J].

PORTA, F ;

CROTTI, C ;

CENINI, S ;

PALMISANO, G .

JOURNAL OF MOLECULAR CATALYSIS, 1989, 50 (03) :333-341

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