NICKEL-CATALYZED DEHYDROGENATION OF AMINES TO NITRILES

被引：73

作者：

YAMAZAKI, S

YAMAZAKI, Y

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1990年 / 63卷 / 01期

关键词：

D O I：

10.1246/bcsj.63.301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aliphatic primary amines having α-methylene underwent oxidative dehydrogenation on treatment with NiSO4 as a catalyst and K2S2O8 as an oxidant to give the corresponding nitriles in good yields. Benzhydrylamine was converted to benzhydrylideneamine quantitatively under the same reaction conditions.

引用

页码：301 / 303

页数：3

共 14 条

[11]

Sheldon R. A., 1981, METAL CATALYZED OXID

[12] REACTION OF LEAD TETRAACETATE WITH PRIMARY AND SECONDARY AMINES CONTAINING AN ALPHA-METHYLENE GROUP [J].