THE SYNTHESIS AND LOW-TEMPERATURE SINGLE-CRYSTAL X-RAY STRUCTURE OF THE CHARGE-TRANSFER COMPLEX ([9]ANES3)2(I2)4 ([9]ANES3=1,4,7-TRITHIACYCLONONANE)

被引：31

作者：

BLAKE, AJ ^{[1
]}

GOULD, RO ^{[1
]}

RADEK, C ^{[1
]}

SCHRODER, M ^{[1
]}

机构：

[1] UNIV EDINBURGH,DEPT CHEM,W MAINS RD,EDINBURGH EH9 3JJ,MIDLOTHIAN,SCOTLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 15期

关键词：

D O I：

10.1039/c39930001191

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [9]aneS3(1,4,7-trithiacyclononane)and I2 in cold CH2Cl2 results in the formation of 1 : 1 and 1 : 2 adducts; the single crystal X-ray structure of the 1 : 2 adduct ([9]aneS3)2(I2)4 shows an unusual polymeric structure with I2 bridging [9]aneS3 thioether units.

引用

页码：1191 / 1193

页数：3

共 21 条

[1] CRYSTAL-STRUCTURE OF ADDITION COMPOUND N-METHYLTHIOCAPROLACTAM-IODINE (1-1) [J].

AHLSEN, EL ;

STROMME, KO .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1974, A 28 (02) :175-184

[2] INTERACTION OF DIIODINE WITH SOME TETRA-SUBSTITUTED DITHIOOXAMIDES - CRYSTAL AND MOLECULAR-STRUCTURE OF BIS(MORPHOLINOTHIOCARBONYL)BIS(DIIODINE) [J].

ATZEI, D ;

DEPLANO, P ;

TROGU, EF ;

BIGOLI, F ;

PELLINGHELLI, MA ;

VACCA, A .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1988, 66 (06) :1483-1489

[3]

BALKE AJ, 1992, J CHEM SOC DA, P2987

[4] STRUCTURAL ISOMERISM IN SILVER THIOETHER MACROCYCLIC CHEMISTRY - THE SYNTHESIS, REDOX PROPERTIES AND CRYSTAL-STRUCTURES OF [AGN([15]ANES5)N][PF6]N, [AG2([15]ANES5)2][BPH4]2 AND [AG([15]ANES5)][B(C6F5)4] ([15]ANES5=1,4,7,10,13-PENTATHIACYCLOPENTADECANE) [J].

BLAKE, AJ ;

COLLISON, D ;

GOULD, RO ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (04) :521-531

[5] BIS(1,4,7-TRITHIACYCLONONANE)GOLD DICATION - A PARAMAGNETIC, MONONUCLEAR AU-II COMPLEX [J].

BLAKE, AJ ;

GREIG, JA ;

HOLDER, AJ ;

HYDE, TI ;

TAYLOR, A ;

SCHRODER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (02) :197-198

[6] CHEMISTRY OF THIOETHER MACROCYCLIC COMPLEXES [J].

Blake, Alexander J. ;

Schroeder, Martin .

ADVANCES IN INORGANIC CHEMISTRY <D>, 1990, 35 :1-80

[7] IS THE MOLECULAR-STRUCTURE OF 1,4,7-TRITHIACYCLONONANE([9]ANES3) AS SYMMETRICAL IN THE GAS-PHASE AS IT IS IN THE CRYSTAL - AN ELECTRON-DIFFRACTION STUDY [J].

BLOM, R ;

RANKIN, DWH ;

ROBERTSON, HE ;

SCHRODER, M ;

TAYLOR, A .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1991, (05) :773-778

[8] THE REFINEMENT OF THE STRUCTURE OF THE COMPLEX OF IODINE WITH 1,4 DITHIANE, C4H8S2.2I2 [J].

CHAO, GY ;

MCCULLOUGH, JD .

ACTA CRYSTALLOGRAPHICA, 1960, 13 (09) :727-732

[9]

COOPER SR, 1990, STRUCT BOND, V72, P1

[10] REACTIONS OF IMIDAZOLE-2-THIONES WITH MOLECULAR-IODINE AND THE STRUCTURES OF 2 CRYSTALLINE MODIFICATIONS OF THE 1-1 1,3-DIMETHYLIMIDAZOLE-2-THIONE-DIIODINE CHARGE-TRANSFER COMPLEX (C5H8I2N2S) [J].

FREEMAN, F ;

ZILLER, JW ;

PO, HN ;

KEINDL, MC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (08) :2586-2591

← 1 2 3 →