A NOVEL AND SIMPLE METHOD FOR THE PREPARATION OF IMINIUM SALTS

被引：19

作者：

JAHN, U ^{[1
]}

SCHROTH, W ^{[1
]}

机构：

[1] MARTIN LUTHER UNIV HALLE WITTENBERG,INST ORGAN CHEM,D-06099 HALLE,GERMANY

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)73799-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alpha-Chloroethers such as chloromethyl alkyl ethers or 1,3,3-trichloro-1-isobutoxyprop-2-enc react with trimethylsilyl-N,N-dialkylamines to give the Mannich-reagent and new 3,3-dichloroprop-2-en-1-ylidene-N,N-dialkyliminium chlorides (vinylogous Viehe-reagents), respectively. Extension of this method leads to the reagent system trimethylsilyl-N,N-dialkylamine/trimethylsilylchloride or -triflate, which allows the direct conversion of carbonyl compounds into iminium salts.

引用

页码：5863 / 5866

页数：4