ALLYLATION OF QUINONES WITH ALLYL(TRIFLUORO)SILANES - DIRECT SYNTHESIS OF ISOPRENOID QUINONES

被引：19

作者：

HAGIWARA, E

HATANAKA, Y

GOHDA, K

HIYAMA, T

机构：

[1] SAGAMI CHEM RES CTR,SAGAMIHARA,KANAGAWA 229,JAPAN

[2] TOKYO INST TECHNOL,RESOURCES UTILIZAT RES LAB,MIDORI KU,YOKOHAMA,KANAGAWA 227,JAPAN

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 16期

关键词：

D O I：

10.1016/0040-4039(95)00394-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allylation of a variety of quinones with allyl(trifluoro)silanes takes place with high regioselectivity in the presence of FeCl3 . 6H(2)O, giving allylquinones in good yields. This method was used to synthesize biologically active isoprenoid quinones such as plastoquinone-l and vitamin K-1.

引用

页码：2773 / 2776

页数：4

共 19 条

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