MOSSBAUER SPECTROSCOPIC STUDIES AND STRUCTURAL CHARACTERIZATION OF OXO-CENTERED TRINUCLEAR IRON CARBOXYLATO-AQUO COMPLEXES

被引：3

作者：

SATO, T

NAKAMOTO, T

KATADA, M

ENDO, K

SANO, H

机构：

[1] SHOWA COLL PHARMACEUT SCI, MICHIDA, TOKYO 194, JAPAN

[2] TOKYO MEETROPOLITAN UNIV, RADIOISOTOPE RES CTR, HACHIOJI, TOKYO 19203, JAPAN

来源：

HYPERFINE INTERACTIONS | 1994年 / 84卷 / 1-4期

关键词：

D O I：

10.1007/BF02060709

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Mixed-valence states of [Fe3O(CH2ClCO2)6(H2O)3]nH2O (n = 0 and 3) were studied by means of Mossbauer spectroscopy and single-crystal X-ray crystallography. The number of water molecules of crystallization was determined by X-ray crystallography. The dehydrated complex was obtained by storing the trihydrated complex under a dry atmosphere. It was found that the temperature dependence of the mixed-valence state is affected by the hydrated water molecules.

引用

页码：559 / 562

页数：4

共 14 条

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[13]

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[14]

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