SYNTHESIS OF [AUFE2(CO)(8)](3-) AND [AU4FE4(CO)(16)](4-) - X-RAY STRUCTURE OF THE [AU4FE4(CO)(16)](4-) CLUSTER ANION IN ITS [NET(4)](+) SALT

被引：31

作者：

ALBANO, VG ^{[1
]}

CALDERONI, F ^{[1
]}

IAPALUCCI, MC ^{[1
]}

LONGONI, G ^{[1
]}

MONARI, M ^{[1
]}

机构：

[1] DIPARTIMENTO CHIM FIS & INORGAN,I-40136 BOLOGNA,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000433

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The new [AuFe2(CO)(8)](3-) and [Au4Fe4(CO)(16)](4-) cluster anions are isolated from the reaction in THF of [Fe(CO)(4)](2-) with [AuBr2](-) salts in molar ratios of 2:1 and 1:1 respectively; as shown by an X-ray investigation on [NEt(4)](4)[Au4Fe4(CO)(16)] the [Au4Fe4(CO)(16)](4-) cluster anion exists in two structural modifications consisting of a square and a rectangle of gold atoms, respectively, bridged by Fe(CO)(4) groups on the edges.

引用

页码：433 / 434

页数：2

共 18 条

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