THE REACTION OF CO2 WITH CH4 TO SYNTHESIZE H-2 AND CO OVER NICKEL-LOADED Y-ZEOLITES

被引：86

作者：

KIM, GJ

CHO, DS

KIM, KH

KIM, JH

机构：

[1] INHA JR TECH COLL,DEPT IND CHEM,INCHON 402751,SOUTH KOREA

[2] TOKYO INST TECHNOL,DEPT CHEM,MEGURO KU,TOKYO 152,JAPAN

来源：

CATALYSIS LETTERS | 1994年 / 28卷 / 01期

关键词：

NICKEL; Y-ZEOLITE; ION EXCHANGE; HYDROGENATION OF CARBON DIOXIDE; METHANE; HYDROGEN; CARBON MONOXIDE; ACID STRENGTH; ELECTROSTATIC FIELD;

D O I：

10.1007/BF00812468

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Nickel metal introduced into Y-zeolite exhibited a high catalytic activity in the dehydrogenation of methane and in the hydrogenation of carbon dioxide with methane to obtain hydrogen and CO at about 850 K. The activity strongly depended on the nickel amount in NaY, and the catalytic properties were influenced by the kind of cations in the Y-zeolite. The higher CO2 conversion was obtained over Ni supported on non-acidic zeolites.

引用

页码：41 / 52

页数：12

共 24 条

[1] INTERACTION OF HYDROGEN, CARBON, ETHYLENE, ACETYLENE, AND ALKYL FRAGMENTS WITH IRON SURFACES - CATALYTIC-HYDROGENATION, DEHYDROGENATION, CARBON BOND BREAKAGE, AND HYDROGEN MOBILITY [J].