THERMOPLASTIC AND SPECTROSCOPIC PROPERTIES OF AMORPHOUS FLUOROPOLYMER THIN-FILMS

被引:9
作者
NASON, TC
LU, TM
机构
[1] Center for Integrated Electronics, Rensselaer Polytechnic Institute, Troy
关键词
Composition - Fluorine containing polymers - Glass transition - Light absorption - Monomers - Nitrogen - Polymerization - Polytetrafluoroethylenes - Pyrolysis - Thermodynamic stability - Thin films - Vacuum applications;
D O I
10.1016/0040-6090(94)90103-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Infrared absorption spectra are reported for fluoropolymer films similar to 0.2 mu m thick produced by vacuum pyrolysis of high polymers of the trade name Teflon AF (Teflon amorphous fluoropolymer). Films were formed using source powders of several mole fractions for the two constituent monomers. Infrared features are identified and interpretations are given for the variation in features with source material composition. Thermal stability and glass transition data in nitrogen are reported for several of the polymer film and source materials. Methods for estimating the stoichiometry in evaporated samples are given.
引用
收藏
页码:27 / 30
页数:4
相关论文
共 7 条