REACTION OF SUBSTITITED PYRIDINES WITH FREE TERTIARY-BUTOXY-RADICALS

被引:11
作者
CHIU, KK
HUANG, HH
机构
[1] Chemistry Department, University of Singapore
来源
JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 19期
关键词
D O I
10.1039/j39690002758
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Substituted pyridines CHR1R2(C5H 4N) are dehydrogenated by free t-butoxy-radicals to the radicals ·CR1R2(C5H4N) which then dimerise to an extent depending on the nature of R1 and R 2. Diphenylacetonitrile and p-nitrocumene undergo similar reactions though 2-methylquinoline is apparently unreactive.
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页码:2758 / &
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