REACTION OF SUBSTITITED PYRIDINES WITH FREE TERTIARY-BUTOXY-RADICALS

被引：11

作者：

CHIU, KK

HUANG, HH

机构：

[1] Chemistry Department, University of Singapore

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 19期

关键词：

D O I：

10.1039/j39690002758

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Substituted pyridines CHR1R2(C5H 4N) are dehydrogenated by free t-butoxy-radicals to the radicals ·CR1R2(C5H4N) which then dimerise to an extent depending on the nature of R1 and R 2. Diphenylacetonitrile and p-nitrocumene undergo similar reactions though 2-methylquinoline is apparently unreactive.

引用

页码：2758 / &

共 23 条

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[14] THE RELATIVE STABILISING INFLUENCES OF SUBSTITUENTS ON FREE ALKYL RADICALS .4. SELECTIVE HYDROGEN-ABSTRACTION BY FREE TERT-BUTOXY-RADICALS
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[15] SYNTHETIC OESTROGENS .1. THE SYNTHESIS OF 2 3-DI-P-HYDROXYPHENYL-2 3-DIMETHYLBUTANE, AN ISOMER OF HEXOESTROL
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[19] HOMOLYTIC REACTIONS OF AROMATIC SIDE CHAINS .2. RELATIVE RATES OF ALPHA-HYDROGEN ABSTRACTION BY TERT-BUTOXY-RADICALS
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