BISTRIPHENYLSILANOL-ASSISTED OXIDATION CATALYZED BY CHROMIUM(VI) OXIDE OF ACTIVATED TRIMETHYLSILYL ETHERS WITH TERT-BUTYL HYDROPEROXIDE

被引：26

作者：

MUZART, J

AJJOU, AN

机构：

[1] Unite de Recherche “Rearrangements Thermiques et Photochimiques”, Associèe au C.N.R.S, Universitè de Reims Champagne-Ardenne, Cedex, B.P.347

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 14期

关键词：

D O I：

10.1080/00397919208021332

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Secondary benzylic or allylic trimethylsilyl ethers are oxidized at room temperature to the corresponding ketones in good yields using aqueous 70% t-BuOOH and catalytic amounts of a mixture of Ph3SiOH and CrO3.

引用

页码：1993 / 1996

页数：4

共 11 条

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[2] CHROMIUM-VI COMPLEX CATALYZED BENZYLIC OXIDATIONS IN THE PRESENCE OF TERT-BUTYL HYDROPEROXIDE
MUZART, J
[J]. TETRAHEDRON LETTERS, 1986, 27 (27) : 3139 - 3142
[3] MUZART J, 1991, SYNLETT, P497
[4] CHROMIUM(VI)-CATALYZED BENZYLIC OXIDATIONS WITH COMMERCIAL TERT-BUTYLHYDROPEROXIDE OR HYDROGEN-PEROXIDE
MUZART, J
AJJOU, AN
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1991, 66 (02): : 155 - 161
[5] CHROMIUM-CATALYZED OXIDATIONS IN ORGANIC-SYNTHESIS
MUZART, J
[J]. CHEMICAL REVIEWS, 1992, 92 (01) : 113 - 140
[6] CHROMIUM-ASSISTED OXIDATIONS WITH SODIUM PERBORATE BY PHASE-TRANSFER CATALYSIS
MUZART, J
AJJOU, AN
[J]. SYNTHETIC COMMUNICATIONS, 1991, 21 (04) : 575 - 580
[7] MUZART J, IN PRESS SYNTHESIS
[8] MUZART J, 1991, IAN SSSR KH, P1454
[9] DIRECT OXIDATION OF BENZYLIC AND ALLYLIC SILYL ETHERS TO CARBONYL-COMPOUNDS
PIVA, O
AMOUGAY, A
PETE, JP
[J]. TETRAHEDRON LETTERS, 1991, 32 (32) : 3993 - 3996
[10] Sharpless K. B., 1979, ALDRICHIM ACTA, V12, P63

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