BISTRIPHENYLSILANOL-ASSISTED OXIDATION CATALYZED BY CHROMIUM(VI) OXIDE OF ACTIVATED TRIMETHYLSILYL ETHERS WITH TERT-BUTYL HYDROPEROXIDE

被引:26
作者
MUZART, J
AJJOU, AN
机构
[1] Unite de Recherche “Rearrangements Thermiques et Photochimiques”, Associèe au C.N.R.S, Universitè de Reims Champagne-Ardenne, Cedex, B.P.347
关键词
D O I
10.1080/00397919208021332
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Secondary benzylic or allylic trimethylsilyl ethers are oxidized at room temperature to the corresponding ketones in good yields using aqueous 70% t-BuOOH and catalytic amounts of a mixture of Ph3SiOH and CrO3.
引用
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页码:1993 / 1996
页数:4
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