SYNTHESES OF RIGID AND SEMIRIGID MOLECULES FOR INVESTIGATIONS OF PHOTOINDUCED ELECTRON-TRANSFER REACTIONS

被引：39

作者：

KUMAR, K ^{[1
]}

TEPPER, RJ ^{[1
]}

ZENG, Y ^{[1
]}

ZIMMT, MB ^{[1
]}

机构：

[1] BROWN UNIV, DEPT CHEM, PROVIDENCE, RI 02912 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1995年 / 60卷 / 13期

关键词：

D O I：

10.1021/jo00118a023

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Investigations of electron transfer reactions in donor-spacer-acceptor (DSA) molecules posessing small numbers of reactive conformations have significantly increased understanding of factors that control transfer rate constants. The syntheses of polynorbornane-based DSA molecules 12, 16, 20, 26, 30, and 34 and heptacyclotetradecane-based DSA molecules 40, 47, 51, and 60 are described. These molecules have been used to explore the effects of electronic symmetry, solvent electronic structure, and temperature on photoinduced electron transfer reactions.

引用

页码：4051 / 4066

页数：16

共 134 条

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